Experimental evaluation of the penetration of TiO2nanoparticles through protective clothing and gloves under conditions simulating occupational use

Abstract

Titanium dioxide nanoparticles (nTiO2) are found in numerous manufactured products. While a few studies have been carried out to measure the efficiency of chemical protective clothing and gloves against nanoparticles (NPs), they have generally not considered the conditions prevailing in occupational settings. This study was designed to evaluate the resistance of protective clothing against NPs under conditions simulating occupational use. Nitrile and butyl rubber gloves, as well as cotton/polyester woven and polyolefin non-woven clothing samples were placed into contact with nTiO2 in the form of powders or colloidal solutions. Simultaneously, mechanical deformations were applied to the samples. Preliminary results showed that nTiO2 may penetrate some of the materials after prolonged dynamic deformations and/or when the NPs are in colloidal solutions. The effect was partly attributed to modifications in the physical and mechanical properties of protective materials that were induced by repetitive mechanica...