Experimental characterisation and further molecular modelling of the conformational and elastic behaviour of poly(ethylene terephthalate) network chains

Abstract

The Monte-Carlo (MC) method developed to model the elastomeric stress–strain behaviour of polyethylene (PE), poly(dimethyl siloxane) (PDMS) and poly(ethylene terephthalate) (PET) networks and the stress-optical behaviour of PE networks is now developed to investigate further the stress–strain behaviour of PET networks. Accurate infrared (IR) spectrometry measurements have been used to determine the populations of gauche conformers in the glycol residues of PET chains in melts. The proportion of gauche states was found to be 76%, consistent with the rotational energy difference of −4.16 kJ mol−1 between trans and gauche states used previously. The greater conformational flexibility of the PET chain compared with the PE chain leads to lower network moduli and smaller deviations from Gaussian and affine network behaviour. Previous results are briefly reviewed and new comparisons of the elastic behaviour of PET and PE chains are made using normalised plots. Subsequent publications will apply the present results to interpreting the measured stress–strain and the stress-optical properties of entangled PET melts.