Experimental and Numerical Study of Radioiodine Sorption and Transport in Hanford Sediments.

Abstract

Radioiodine (129I) poses a potential risk to human health and the environment at several U.S. Department of Energy sites, including the Hanford Site, located in southeastern Washington State. Experimental studies and numerical modeling were performed to provide a technical basis for field-scale modeling of iodine sorption and transport behavior. The experiments were carried out using six columns of repacked contaminated sediments from the Hanford Site. Although iodate has been determined to be the dominant iodine species at the Hanford Site, the sorption and transport behaviors of different iodine species were investigated in a series of column experiments by first leaching sediments with artificial groundwater (AGW) followed by AGW containing iodate (IO3-), iodide (I-), or organo-iodine (2-iodo-5-methoxyphenol, C7H7IO2). Ferrihydrite amendments were added to the sediments for three of the columns to evaluate the impact of ferrihydrite on 129I attenuation. The results showed that ferrihydrite enhanced the iodate sorption capacity of the sediment and retarded the transport but had little effect on iodide or organo-I, providing a technical basis for developing a ferrihydrite-based remedial strategy for iodate under oxidizing conditions. Data from the column transport experiments were modeled using the linear equilibrium Freundlich isotherm model, the kinetic Langmuir adsorption model, and a distributed rate model. Comparisons of the experimental data and modeling results indicated that sorption was best represented with the distributed rate model with rates and maximum sorption extents varying by iodine species and ferrihydrite treatment. However, the linear Freundlich isotherm (Kd) model was also found to fit the laboratory experimental data relatively well, suggesting that the Kd model could also be used to represent iodine transport at the field scale.