Abstract

The CuSO4 aqueous solution electrolysis experiment is conducted to investigate the electrical bubble dynamics using the slotted anode to reveal the gas removal mechanism. A three-dimensional transient mathematical model coupled discrete phase model (DPM) − discrete-continuum transition model (DCTM) − volume of fluid (VOF) method is developed to track the dispersed bubble trajectory, bridge the dispersed bubble to continuous gas, and resolve the deformed bubble surface, respectively. The slotted anode decreases the bubble diameter compared with the traditional anode because the slot shortens the bubble motion distance to decrease the bubble residence time. The slot width smaller than the detached bubble diameter can limit the bubble deformation. Increasing current plays a dual role in bubble motion in the experiment: it accelerates the bubble coalescence process but decreases the bubble collision probability. The longitudinal slot is more conducive to reducing the maximum bubble coverage and increasing the bubble release frequency than the transverse slot.

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