Experiment and simulation of non-catalytic thermal decomposition of CH4 for CO2-free hydrogen production in a vertical tube

Abstract

To address climate change issues, there has been growing interest in low-carbon H2 production technologies with the potential for zero-CO2 emissions. Non-oxidative CH4 pyrolysis is a promising method for producing H2 and solid carbon without generating CO2 emissions. This study presents experimental and numerical studies on non-catalytic CH4 pyrolysis using a vertical tube reactor (28 mm in diameter and 1800 mm in height). A three-dimensional (3D) Eulerian computational fluid dynamics (CFD) model coupled with chemical reaction and heat transfer was developed and validated against the experimentally determined axial temperature profiles and methane conversion (XCH4). The hydrodynamics, reaction kinetics, and heat transfer characteristics were investigated using the validated CFD model. The highest XCH4 of 99% was achieved at 1200 °C with a gas flow rate of 0.5 LPM. Heat transfer combined with natural and forced convection was confirmed by the CFD simulation of the tubular reactor. The heat transfer coefficient in the reaction zone ranged from 43 to 46 W/m2/°C. The CFD simulation served as a viable tool for examining the influence of the hydrodynamics, heat transfer, and reaction kinetics on the performance of the reactor with a given geometry and under specified operating conditions in non-catalytic CH4 pyrolysis.