Abstract

1-Vinylpyrrole-2-carbaldehydes and 1-vinyl-4,5-dihydrobenzo[ g]indole-2-carbaldehyde were synthesized in 56–91% yields from their 1-vinyl derivatives by a modified Vilsmeier–Haack reaction. A low temperature (−78 °C) is required to avoid removal of the N-vinyl group, whereas at elevated temperature (reflux in 1,2-dichloroethane) the latter process leads to direct conversion of 1-vinylpyrroles to pyrrole-2-carbaldehydes.

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