Abstract
The rates of fluid solution emission decay (kobs) for planar Pt(diimine)X2 complexes (X = CN, aryl(acetylide), 1/2 toluene-3,4-dithiolate(tdt)) decrease with increasing concentration indicative of self-quenching. Values of kobs are obtained from a modified Stern−Volmer expression and approach the diffusion limit by association of excited- and ground-state monomers, possibly via Pt···Pt interaction. For Pt(phen)(CCPh)2, self-quenching is accompanied by excimer emission.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
