Abstract
The effect of repulsive interactions (geometrical packing of molecules) on mixing properties is examined considering hard sphere solutes of different diameters in the hard sphere and pseudo-hard body solvents. It is shown that the fluid of pseudo-hard bodies, representing repulsive interactions in water, captures, without any parameter adjustment, the experimentally observed decrease of the partial molar volume of nonpolar solutes (hard spheres) at their low concentrations when compared to that in a nonpolar (hard sphere) solvent.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
