Abstract
The excess mixing functions of hydrocarbons of various structure and primary alcohols in glass-like polyvinyl trimethylsilane and hydrocarbons in natural rubber and PDMS are determined by a reverse gas chromatography method. The exothermal character of the mixing, the high entropy effects, and the marked dependence of the excess mixing functions on the molar volume of the sorbate in glass-like polymers and dissolution in associated liquids.
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