Abstract
Microcombustion attracts interest with its promise of energy dense power generation for electronics. Yet, challenges remain to develop this technology further. Thermal management of heat losses is a known hurdle. Simultaneously, non-uniformities in heat release within the reaction regions also affect the device performance. Therefore a combination of thermal management strategies are necessary for further performance enhancements. Here, a bench top platinum nanoparticle based microcombustion reactor, coupled with thermoelectric generators is used. Methanol-air mixtures achieve room temperature ignition within a catalytic cartridge. In the current study, the reactor design is modified to incorporate two traditional thermal management strategies. By limiting enthalpic losses through the exhaust and reactor sides, using multi-pass preheating channels and heat recirculation, expected improvements are achieved. The combined strategies doubled the power output to 1.01 W when compared to the previous design. Furthermore, a preliminary study of catalyst distribution is presented to mitigate non-uniform catalytic activity within the substrate. To do this, tailored distribution of catalyst particles was investigated. This investigation shows a proof-of-concept to achieve localized control, thus management, over heat generation within substrates. By optimizing heat generation, a highly refined combustion-based portable power devices can be envisioned.
Highlights
These results are for an air flow rate of 6000 mL/min through a 2SSC substrate and correspond well to the previous conditions used with this facility
The results show that local substrate temperatures, and catalytic activities, can be controlled by selectively changing local catalyst distribution
The catalytic cartridge design affords easy replenishment of the device. This highly reconfigurable reactor served as an ideal platform for examining a range of thermal management strategies to improve device performance
Summary
Academic Editors: Reza Behi, Masud Behnia and Hamidreza Behi. Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. As the worldwide need for electrical power grows, new, improved, and mobile methods of harvesting energy become more critical. Thermoelectric generation using catalyzed microcombustion is a strong candidate with many advantages. Rapid recharging is available with the use of hydrocarbon fuels. Devices can be compact and more energy dense compared to commonly used consumer batteries [1,2]. Battery disposal is eliminated, which prevents potential leaking of hazardous metals into the environment [3]
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