Abstract

In this paper, the photoluminescence spectra and the electron paramagnetic resonance spectra of the Cr3+ ions in the KMgF3 crystal are explained based on the complete energy matrix diagonalization procedure and a crystal–field like model. The results agree well with the experimental data. It is also shown that the nearest neighbor F− ions deviate 1.3981 and −0.486° from their original position because of the K+ vacancy.

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