Abstract
The influence of the hydrogen and vacancies introduced into an alloy matrix as a result of electrolytic hydrogenation on the structural state of Pd–11.3 at % W alloy after fourfold hydrogenation has been studied. It is established that nonmonotonic changes in the sample defect structure are determined by the transformation of single vacancies into vacancy complexes (micropores and small dislocation loops), their decay during relaxation, and migration of vacancies from the matrix to the boundaries of coherent-scattering regions (CSRs) and backwards. The vacancy transformation rate into defect complexes depends on their concentration. Long-term relaxation of the alloy leads to almost complete transfer of vacancies from the matrix to the CSR boundaries. An interpretation of the obtained experimental data within the theory of development of hierarchical defect structures is proposed.
Published Version
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