Evolution of polarization crystallites in 0.92BaTiO3-0.08Bi(Ni0.5Zr0.5)O3 microcrystal-amorphous composite thin film with high energy storage capability and thermal stability

Abstract

• A new-type microcrystal-amorphous composite films of 0.92BaTiO 3 -0.08Bi(Ni 0.5 Zr 0.5 )O 3 . • Evolution of polarization crystallites in microcrystal-amorphous composite film. • A high energy storage density of 103.7 J cm −3 is obtained at 8.3MV cm −1 . • Excellent dielectric and energy storage stabilities are achieved in a wide range. Thin film capacitors with large energy storage density and high breakdown strength are widely used in modern electronic fields. To solve the problems of interface effect and different polarization mechanism between matrix and fillers in conventional heterogeneous structure composite thin film capacitors, a new-type inorganic microcrystal-amorphous composite film of 0.92BaTiO 3 -0.08Bi(Ni 0.5 Zr 0.5 )O 3 (0.92BT-0.08BNZ) are prepared by sol–gel method. The amorphous matrix improving the breakdown strength is introduced into the film by adjusting preparation technology. Moreover, the nano-scale polar microcrystalline regions (fillers) are introduced and uniformly distributed in the amorphous matrix under various annealing temperatures. Through investigating the influence of different amorphous matrix and microcrystal trend on the dielectric and energy storage properties, it is found that synergistic effect between the polarized microcrystalline regions and the amorphous matrix are optimal at an annealed temperature of 550 ℃. The result shows that a high energy storage density of 103.7 J cm −3 and an efficiency of 88.3% are obtained under the electric field of 8.30MV cm −1 . Simultaneously, the excellent dielectric and energy storage stability is achieved in a wide temperature range of 20–200 °C. Conclusively, this microcrystal-amorphous composite film overcome the low energy storage capability and poor thermal stability of conventional composite films and provide a feasible way for preparing high energy storage performance films.