Evidence of Reactivity in the Membrane for the Unstable Monochloramine during MIMS Analysis.

Essyllt Louarn,Julien Leprovost,Abdoul Monem Asri-Idlibi,Hélène Mestdagh,Michel Héninger

doi:10.3390/s18124252

Abstract

Membrane Inlet Mass Spectrometry (MIMS) was used to analyze monochloramine solutions (NH2Cl) and ammonia solutions in a compact FTICR. Chemical ionization enables identification and quantification of the products present in the permeate. The responses of protonated monochloramine and ammonium increase linearly with the solution concentration. The enrichments were respectively 1.2 and 5.5. Pervaporation is dependent on pH and only the basic form of ammonia NH3 pervaporates through the membrane. Unexpectedly, the small ammonia molecule permeated very slowly. It could be due to interactions with water molecules inside the membrane that create clusters. Moreover, NH2Cl solutions, in addition to the NH3Cl+ signal, presented a strong NH4+ signal at m/z 18.034. Ammonia presence in the low-pressure zone before ionization is probable as NH4+ was detected with all the precursors used, particularly CF3+ and trimethylbenzene that presents a proton affinity higher than monochloramine. Ammonia may be formed inside the membrane due to the fact that NH2Cl is unstable and may react with the water present in the membrane. Those results highlight the need for caution when dealing with chloramines in MIMS and more generally with unstable molecules.

Highlights

Membrane Inlet Mass Spectrometry (MIMS) is an efficient tool to analyze water and air samples from the environment
This study presents new results on chloramine and ammonia detection by MIMS in aqueous solutions
The steady state response of ammonia and monochloramine are in accordance with their high solubility in water

Summary

Introduction

Membrane Inlet Mass Spectrometry (MIMS) is an efficient tool to analyze water and air samples from the environment. It has gained interest since it was first reported in 1987 [1] as it allows real-time analysis of water and air samples by mass spectrometry [2] and generally preconcentration of targeted compounds. Its use spans from detection of organics in water to the more recent analysis of nitrites and nitrates [3]. MIMS technology is based on the separation of the analyte stream and the mass spectrometer inlet by a membrane. Compared to more traditional GC-MS instruments used for volatile organic compounds (VOC) analysis, MIMS results in rapid analysis without complex preparation of the samples [4]

Methods

Results

Conclusion