Abstract

The acoustic levitation method (ALM) is expected to be applied as a container-less processing technology in the material science, analytical chemistry, biomedical technology, and food science domains because this method can be used to levitate any sample in mid-air and prevent nucleation and contamination due to the container wall. However, this approach can lead to nonlinear behavior, such as acoustic streaming, which promotes the evaporation of a levitated droplet. This study aims to understand the evaporation and precipitation kinetics of an acoustically levitated multicomponent droplet. An experimental investigation of the evaporation process of a salt solution droplet was performed, and the experimental results were compared with those of the d2-law. The droplet was noted to evaporate in two stages owing to the precipitation of the salt. Because of the vapor pressure depression, the experimental data did not agree with the classical prediction obtained using the d2-law. However, the experimental results were in partial agreement with those of the d2-law when the vapor pressure depression was considered by using the concentration estimate at each time, as obtained from the experimental results. In addition, it was observed that the time when the salt completely precipitated could be estimated by using the extended theory. These findings provide physical and practical insights into the droplet evaporation mid-air for potential lab-in-a-drop applications.

Highlights

  • Evaporation of droplets is a fundamental phenomenon in nature

  • The dynamics of evaporation for sessile droplets on a solid substrate have been extensively studied over the past decades.[1,2,3,4,5]

  • The reason for the surface temperature becoming constant at a temperature 2 C higher than the room temperature is thought to be due to a deviation from the initial emissivity of 0.96, owing to the complete precipitation of the salt

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Summary

Introduction

The dynamics of evaporation for sessile droplets on a solid substrate have been extensively studied over the past decades.[1,2,3,4,5] While it is useful to investigate the evaporation behavior of sessile droplets, complex wetting dynamics by the interaction between the droplet and solid substrate should be taken into account to understand the nature of the evaporation. Zang et al used ALM to generate bubbles for industries pertaining to inorganic salts, food, cosmetics, and materials.[15,16]

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