Abstract

A novel integrated water vapor (IWV) product from TROPOspheric Monitoring Instrument (TROPOMI) is validated together with a Global Ozone Monitoring Instrument-2 (GOME-2) standard product. As reference, ground-based Global Navigation Satellite Systems (GNSS) IWV data in 235 European stations from May 2018 to May 2019 are used. Under cloud free situations, a general comparison is carried out. It suggests that TROPOMI IWV exhibits less bias than GOME-2 and better results in the dispersion and regression parameters. Moreover, TROPOMI presents more homogeneous results along the different stations. However, TROPOMI is found to be overestimating the IWV uncertainties and being, therefore, too conservative in the confidence interval considered. The dependence of satellite product performance on several variables is also discussed. TROPOMI IWV shows wet bias of 5.7% or less for IWV < 10 mm (TROPOMI) and dry bias of up to −3% (TROPOMI). In contrast, GOME-2 shows wet bias of 30% or less for IWV < 25 mm (GOME-2) and dry bias of −12.3% for IWV > 25 mm. In addition, relative standard deviation (rSD) increases as IWV increases. In addition, the dependence on solar zenith angle (SZA) was also analyzed, as solar radiation bands are used in the retrieval algorithm of both instruments. Relative mean bias error (rMBE) shows positive values for GOME-2, slightly increasing with SZA, while TROPOMI shows more stable values. However, under high SZA, GOME-2 IWV exhibits a steep increase in rMBE (overestimation), while TROPOMI IWV exhibits a moderate decrease (underestimation). rSD is slightly increasing with SZA. The influence of cloudiness on satellite IWV observations is such that TROPOMI tends to overestimate IWV more as cloudiness increases, especially for high IWV. In the case of GOME-2, the rSD slightly increases with cloudiness, but TROPOMI rSD has a marked increase with increasing cloudiness. TROPOMI IWV is an important source of information about moisture, but its algorithm could still benefit from further improvement to respond better to cloudy situations.

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