Evaluation of Physicochemical Parameters of Biosorbents Produced from Groundnut Hull Using Microwave Assisted Irradiation Method

Abstract

Samples of ground nut hull were converted to biosorbents using microwave assisted method [groundnut hull treated with hydrogen peroxide (HP-GH), groundnut hull treated with distilled water (W-GH) and raw groundnut hull (R-GH)]. The biosorbents were further characterized using physicochemical procedures (pH dependence, bulk density, surface area, ash content, and volatile matter, moisture content). The results show that HP-GH has pH = 8.9, W-GH pH = 8.4 and R-GH pH = 8.5 which is an indication that all the biosorbents have the appropriate pH values for the uptake of cationic species within aqueous systems. Surface area analysis revealed that HP-GH has the largest surface area (74.20 m2·g-1) while W-GH and R-GH have surface area values of 29.40 m2·g-1 and 21.40 m2·g-1 respectively. This suggests that modification of raw groundnut hull biomass with hydrogen peroxide possibly instigated delignification of the biomass which resulted in increased surface area for HP-GH. Results from Bulk density analysis also confirm the data obtained from surface area analysis. Accordingly, R-GH displayed the highest bulk density followed by W-GH with HP-GH showing the least bulk density. The variation in pH values among the biomass used in this study may be explained by the variation in their ash content as well because pH and ash content are positively correlated. Hence, HP-GH with a pH = 8.9 has high ash content (117.31%), W-GH with pH = 8.4 has 97.93% ash content and R-GH with pH = 8.5 has 94.26% ash content. Results from moisture content analysis show that HP-GH (99.95%), W-GH (99.97%) and R-GH (99.89%) may necessitate exposure of the biosorbents to moderate heat before use. The results obtained from this study suggest that modification of ground nut hull with either distilled water or Hydrogen peroxide by means of microwave irradiation improves physicochemical properties which may perhaps increase the adsorption capacity of the biomass.