Abstract

The calibration of ASMs is a prerequisite for their application to simulation of a wastewater treatment plant. This work should be made based on the evaluation of structural identifiability of model parameters. An EBPR sub-model including denitrification phosphorus removal has been incorporated in ASM2d. Yet no report is presented on the structural identifiability of the parameters in the EBPR sub-model. In this paper, the differential algebra approach was used to address this issue. The results showed that the structural identifiability of parameters in the EBPR sub-model could be improved by increasing the measured variables. The reduction factor η NO 3 was identifiable when combined data of aerobic process and anoxic process were assumed. For K PP , X PAO and q PHA of the anaerobic process to be uniquely identifiable, one of them is needed to be determined by other ways. Likewise, if prior information on one of the parameters, K PHA , X PAO and q PP of the aerobic process, is known, all the parameters are identifiable. The above results could be of interest to the parameter estimation of the EBPR sub-model. The algorithm proposed in the paper is also suitable for other sub-models of ASMs.

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