Evaluating the release risk of potentially toxic elements from sediments in the New Zhuzhao River Estuary of Nansi Lake, using high-resolution technology and sequential extraction.

Abstract

Potentially toxic elements (PTEs) re-release from sediment is an essential process in the sediment-water interface (SWI), especially for the influent river estuary as an important accumulation site. In this study, the diffusive gradient in thin films (DGT), high-resolution dialysis (HR-peeper) technique, and BCR sequential extraction were employed to evaluate the release risk of PTEs (As, Cu, Pb, Zn, Cd) in the New Zhuzhao River Estuary of Nansi Lake. Results showed that Cd existed primarily in the non-residual fraction (accounting for 59.87%), and the residual fractions of As, Cu, Pb, and Zn accounted for a greater proportion (12.65 to 33.07%). The mobility of Cd was the highest with a risk assessment code of 33.53% reaching the medium risk category. The resupply capacity calculated by CDGT/CDis showed that As was the largest, with an average value of 0.43, indicating the strongest release capacity of As from the sediment to pore water. Furthermore, the diffusive fluxes using DGT and HR-peeper showed that As possesses a much higher potential to release upward overlying water than other elements.