Abstract

In the title compound, C17H16ClNO2, the N=C—O—C—C fragment is planar within 0.029 (1) Å, and makes dihedral angles of 66.71 (8) and 59.61 (8)° with the planes of the chloro­phenyl and benzoyl rings, respectively. The carbonyl C=O bond is not coplanar with either of the aromatic rings; it makes angles of 42.5 and 23.5° with the normals to the ring planes. In the crystal, very weak C—H⋯O, C—H⋯Cl, C—H⋯π and π–π [inter­planar distance = 3.53 (1) Å] inter­actions are observed.

Highlights

  • In the title compound, C17H16ClNO2, the N C—O—C—C fragment is planar within 0.029 (1) Å, and makes dihedral angles of 66.71 (8) and 59.61 (8) with the planes of the chlorophenyl and benzoyl rings, respectively

  • CgA denotes the centroid of the phenyl ring C1–C6

  • Symmetry codes: (i) x, y+1, z; (ii) −x+2, −y+1, −z+1; (iii) x+1, y, z; (iv) x+1, y−1, z; (v) −x+2, −y+1, −z+2

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Summary

Agilent Xcalibur Eos diffractometer

Refinement a Department of Studies in Chemistry, University of Mysore, Mysore 570 006, India, and bDepartment of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60780 Poznań, Poland. R factor = 0.044; wR factor = 0.117; data-to-parameter ratio = 17.6. CgA denotes the centroid of the phenyl ring C1–C6. C17H16ClNO2, the N C—O—C—C fragment is planar within 0.029 (1) Å, and makes dihedral angles of 66.71 (8) and 59.61 (8) with the planes of the chlorophenyl and benzoyl rings, respectively. C O bond is not coplanar with either of the aromatic rings; it makes angles of 42.5 and 23.5 with the normals to the ring planes. H and – [interplanar distance = 3.53 (1) Å] interactions are observed

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