Abstract

In the title compound, C14H12ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C=O bond. The benzoyl and aniline benzene rings are tilted relative to each other by 82.8 (1)°. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into infinite chains running along the c-axis direction.

Highlights

  • In the title compound, C14H12ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C O bond

  • Intermolecular N—HÁ Á ÁO hydrogen bonds link the molecules into infinite chains running along the c-axis direction

  • Absorption correction: analytical [CrysAlis RED (Oxford Diffraction, 2009), based on expressions derived from Clark &

Read more

Summary

Structure Reports Online

Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.004 A; R factor = 0.057; wR factor = 0.138; data-to-parameter ratio = 23.3. C14H12ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C O bond. The benzoyl and aniline benzene rings are tilted relative to each other by 82.8 (1). Intermolecular N—HÁ Á ÁO hydrogen bonds link the molecules into infinite chains running along the c-axis direction. Related literature For the preparation of the title compound, see: Gowda et al (2003). For studies on the effects of substituents on the structures and other aspects of N-(aryl)-amides, see: Bowes et al (2003); Gowda et al (2000); Saeed et al (2010), on N-(aryl)methanesulfonamides, see: Gowda et al (2007), on N-(aryl)arylsulfonamides, see: Shetty & Gowda (2005) and on Nchloro-arylsulfonamides, see: Gowda & Shetty (2004)

Oxford Diffraction Xcalibur Ruby Gemini diffractometer
HÁ Á ÁA
Special details

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.