Abstract
In the structure of the the title compound, C15H14ClNO, the N—H and C=O bonds are trans to each other and the amide O atom is anti to the ortho-Cl atom in the benzoyl ring. The amide group makes dihedral angles of 61.2 (6) and 42.2 (8)° with the benzoyl and aniline rings, respectively. In the crystal, the molecules are linked into infinite chains by N—H⋯O hydrogen bonds.
Highlights
In the structure of the the title compound, C15H14ClNO, the N—H and C O bonds are trans to each other and the amide O atom is anti to the ortho-Cl atom in the benzoyl ring
The molecules are linked into infinite chains by N—HÁ Á ÁO hydrogen bonds
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: NG2536)
Summary
Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.003 A; R factor = 0.031; wR factor = 0.083; data-to-parameter ratio = 11.4. In the structure of the the title compound, C15H14ClNO, the N—H and C O bonds are trans to each other and the amide O atom is anti to the ortho-Cl atom in the benzoyl ring. The amide group makes dihedral angles of 61.2 (6) and 42.2 (8) with the benzoyl and aniline rings, respectively. The molecules are linked into infinite chains by N—HÁ Á ÁO hydrogen bonds. Related literature For the synthesis, see: Gowda et al (2003). For structure of the 3,5-dichlorophenyl analog and other benzanilides, see: Gowda et al (2008a,b)
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