Abstract
In this work, the process for ethyl ester production is studied using refined sunflower oil, and NaOH, KOH, CH3ONa, and CH3OK, as catalysts. In all cases, the reaction is carried out in a single reaction step. The best conversion is obtained when the catalyst is either sodium methoxide or potassium methoxide. We found that during the transesterification with ethanol, soap formation is more important than in the case of methanol. The saponification reaction consumes an important fraction of the catalyst. The amount of catalyst consumed by this reaction is 100% in the case of using hydroxides as catalyst (KOH or NaOH), and 25%, and 28% when using CH3ONa and CH3OK as catalysts, respectively. Ethanol increases the catalyst solubility in the oil–ethyl ester phase, thus accelerating the saponification reaction.It is possible to obtain high conversions in a one-step reaction, with a total glycerine concentration close to 0.25%.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
