Estimation of transport hydraulic parameters in loessic sediment, Argentina: Application of column tests

Abstract

Dispersivity and porosity parameters needed to simulate flow and non-reactive transport were calculated and validated for loess-like sediments of the Pampean aquifer located in southeastern Buenos Aires province, Argentina, using infiltration experiments in laboratory columns filled with selected undisturbed sediment. To obtain values for these parameters, the experimental curves of arrival for chloride were visually adjusted to the curves obtained from numerical simulation using PHREEQC 2.0. Visual adjustment consisted of trying different parameter values until the most representative one was obtained. The best adjustment was obtained for dispersivity and porosity values of 0.01 m and 0.35, respectively. Since analytical solutions for the flow and transport equations are applicable to simplified cases such as this, an attempt was made to adjust the parameters automatically, using a model based on this type of solution. This automated analytical solution was developed using the Fortran programming language, and the automatic parameter calibration was achieved by minimizing the distance between the observed and calculated values of two parameters. The automated technique gave values of 0.0084 m and 0.39 for dispersivity and porosity, respectively. The sediments studied here constitute the uppermost unit of the Pampean aquifer. Given the relevance of this layer and the growing anthropic influence on it, parameter quantification is important for both laboratory tests and for hydrogeochemical simulations that investigate contaminant transport.