Abstract

Combustion of aluminium particles was observed with fast tine camera and light chopper techniques. The burning times, appearance of the flame, oxide particle size and oxide shape, including hollow oxide spheres, did not support the diffusion flame theory. An alternative combustion model, which assumes that diffusion through the oxide layer surrounding the metal droplet is the rate-controlling step, gave reasonably good agreement with experiment. Inadequate knowledge about diffusion coefficients in liquid alumina is the principal uncertainty involved. Metal boiling causes expansion of the oxide shell and accounts for the prevalence of hollow oxide spheres in the combustion products.

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