Abstract
The reaction of phosphoryl radicals with (η2-C60)lrH(CO)(PPh3)2 and (η2-C60IrH(8H12)(PPh3) was shown (ESR) to result in the formation of isomers differing in the constants of hyperfine interaction (HFI) with31P nuclei,g-factors, and linewidths. It is likely that the addition of phosphoryl radicals at a distance of two-three bond lengths from the metallofragment is predominant.
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