Abstract
Abstract Based on the spin density calculated in our previous paper, the ESR spectra of the benzene anion (exactly the dihydrophenylide ion) are analyzed by the Bloch equation. A hyperfine spectrum broader than those of usual aromatic radicals attributes to the chemical exchange process that the ion in question surrounded by solvent molecules undergoes a rotational motion characterized by the time τ which is the life time of chemical exchange. The line shape for each hyperfine spectrum is given in terms of 1⁄T2 and τ under the condition of τ⁄T2<<1.
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