Erratum to: “The Fluorescence and Electronic Structure of Phenyl-Substituted Tetraazachlorin Molecules” [Optics and Spectroscopy 117, 722 (2014)

Abstract

should read “porphyrazine” instead of “porphyrazin”; should read “intersystem crossing” instead of “intercombinational conversion”; should read “mirror-symmetrical” instead of “reflection-symmetric”; should read “fluorescence enhancement” instead of “fluorescence buildup.” Page 722, Abstract, lines 9–10 from the top, the sentence should read: This characteristic increases upon tetrapyrrole phenylation. Page 727, left column, lines 17–18 from the top, the sentence should read: The vibronic transition parts of the emission spectrum are diffuse, (…) Page 727, left column, lines 29–30 from the top, the sentence should read: Note that the Stokes shift in these cases is relatively large. Page 729, left column, lines 8–10 from the bottom, the sentence should read: For H2Ph8TACmp and H2Ph6TACtm, the enhancement of fluorescence is weaker than in the former case: on cooling, τF is increased by a factor of 4–5 in MTHF and by a factor of only 2.6–3 in toluene. Page 729, right column, lines 9–10 from the footnote, the sentence should read: It is seen from Table 1 that our results agree reasonably well with previously reported data. Page 730, left column, lines 16–19 from the top, the sentence should read: The lifetime for the outgassed H2TAP solution in toluene (τT0) was measured by A.S. Stasheuski as phosphorescence decay at λreg = 1070 nm using the setup described in [29]. Page 730, left column, lines 20–23 from the top, the sentence should read: The τT value derived from the kinetics of the rise of singlet oxygen luminescence [26] for the nonoutgassed solution at λreg = 1272 nm is 162 ns; Page 730, right column, lines 25–27 from the top, the sentence should read: Therefore, for H2TAP (λF00≈ 620 nm), the internal conversion probability should not be high. Page 731, left column, the heading of Table 2 should read: Bond lengths in the porphine macrocycle (A). Page 731, left column, lines 3–6 from the top, the sentence should read: For elucidating the mechanism of the deactivation of the S1 state, it was of essential interest to see whether the enhancement of H2TAP fluorescence would be observed at 77 K. Page 733, left column, lines 2–3 from the top, the sentence should read: The corresponding difference for the H2P–H2C pair is 0.013 A. Page 733, left column, lines 14–16 from the top, the sentence should read: The macrocycle undergoes additional contraction, and the symmetry of its conjugated system is very close to D2h. Page 733, right column, line 21 from the top should read: Replacement of the methine bridges (…) Page 734, left column, lines 8–11 from the figure caption, the sentence should read: This is the main reason of the large bathochromic shift of the Soret band of H2Ph8TAP and MgPh8TAP [16] relative to H2TAP and MgTAP, respectively. Page 734, left column, lines 1–4 from the bottom, the sentence should read: The complete INDO/Sm calculation yields the corresponding quantitative characteristics, which are in good agreement with experimental data (see below). Page 740, left column, reference no. 25 should read: 25. V. A. Galievsky, A. S. Stasheuski, V. V. Kiselyov, A. I. Shabusov, M. V. Belkov, and B. M. Dzhagarov, Instrum. Exp. Tech. 53, 568 (2010). 25. V. A. Galievsky, A. S. Stasheuski, V. V. Kiselyov, A. I. Shabusov, M. V. Belkov, and B. M. Dzhagarov, Instrum. Exp. Tech. 53, 568 (2010). 30. V. L. Ermolaev and E. B. Sveshnikova, Acta Phys. Pol. 34, 771 (1968).