Abstract
The flow behavior of the supercooled Zr 41.2Ti 13.8Cu 12.5Ni 10Be 22.5 bulk metallic glass-forming liquid is studied in isothermal three-point beam-bending experiments. The experiments lead to the determination of the equilibrium viscosity as a function of temperature. Comparison with other glass-forming liquids shows that the Zr 41.2Ti 13.8Cu 12.5Ni 10Be 22.5 alloy is a strong liquid, similar to sodium silicate liquids. Flow measurements during phase separation and subsequent formation of crystals embedded in a non-crystalline matrix reveal a dramatic slowdown of the kinetics of the matrix that is expressed in an increase of the viscosity by several orders of magnitude.
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