Abstract
An equilibrium theory of the separation of two-component gaseous mixtures via the pressure swing adsorption process known as heatless adsorption is presented. Both components of the mixture are adsorbable. One is present at a trace level and is preferentially adsorbed. Principal predictions of the theory for the condition of complete removal of the trace component from the high pressure product stream when using the least possible amount of adsorbent are as follows. When the separation factor is large, high recovery of purified high pressure product is obtained and blowdown and purge losses are small. Recovery is increased and losses decreased by increasing the pressure ratio. Conversely, recovery of the purif high pressure product is small and blowdown and purge losses are large when the separation factor is small. In this case the use of high pressure ratio not improve performance. The trace level component in the combined blowdown and purge stream is derived increasingly from the blowdown as the pressure ratio is increased.
Published Version
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