Abstract
The ion exchange equilibrium of cobalt, nickel and copper metal ions/H+ system were studied on Titanium(IV) antimonate in aqueous media at 30, 40 and 60 °C. On the basis of particle diffusion control different physical parameters e.g. the effective diffusion coefficients, activation energy and entropy of activation have been evaluated. Capacity measurements and titration curves have been determined. The obtained data were compared to those organic resin and inorganic ion exchangers. The influence of coordination number and the cation structure on the exchange mechanism have been studied on the light of the thermodynamic properties.
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