Abstract
The aim of this study is to show the influence of the repulsive part of the intermolecular potential on the thermodynamical properties of hot gases at high pressures. For this purpose, a new model of equation of state, based on intermolecular potentials, has been built for gases at high temperature throughout a large range of pressure (1 bar to 0.5 Mbar). Two equations of state, based on this model, are compared in order to show the influence of the repulsive exponent of the potential on the thermodynamic properties of detonation products. Calculated results are compared to experimental data.
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