Abstract
The angular dependence of the EPR spectra of irradiated single crystals of potassium azide has been measured at room temperature. As a result, by comparison of spectroscopic splitting factors and hyperfine splittings, one of the defects present can be identified as an NO2−− radical existing in an orientation different from that previously reported. Crystal symmetry and the symmetry of the angular dependence of the EPR spectra indicate that this alternate orientation is such that the axis which is perpendicular to the plane of the NO2−− radical lies in either the [110] or the [11̄0] direction of the crystal.
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