Abstract
The hexamethylethane radical cation (Me/sub 3/C.CMe/sub 3/)/sup +/ has been generated through positive charge transfer by ..gamma.. irradiation of both glassy and polycrystalline Freon solutions, its EPR spectrum consisting of seven lines with binomial intensities and having the parameters /sup 1/A(6) = 29.0 +- 0.2 G and g = 2.0031 +- 0.0003. In contrast, only neutral alkyl radicals are produced from the hydrocarbon by ..gamma.. irradiation of the hexamethylethane matrix, even when powerful electron scavengers are present. It is suggested that the formation of the radical cation by positive charge transfer in a Freon matrix is a more relaxed process than that of vertical ionization by electron impact in a hexamethylethane matrix.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
