Environmental sustainability of biofuels: a review.

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Abstract
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Biofuels are being promoted as a low-carbon alternative to fossil fuels as they could help to reduce greenhouse gas (GHG) emissions and the related climate change impact from transport. However, there are also concerns that their wider deployment could lead to unintended environmental consequences. Numerous life cycle assessment (LCA) studies have considered the climate change and other environmental impacts of biofuels. However, their findings are often conflicting, with a wide variation in the estimates. Thus, the aim of this paper is to review and analyse the latest available evidence to provide a greater clarity and understanding of the environmental impacts of different liquid biofuels. It is evident from the review that the outcomes of LCA studies are highly situational and dependent on many factors, including the type of feedstock, production routes, data variations and methodological choices. Despite this, the existing evidence suggests that, if no land-use change (LUC) is involved, first-generation biofuels can—on average—have lower GHG emissions than fossil fuels, but the reductions for most feedstocks are insufficient to meet the GHG savings required by the EU Renewable Energy Directive (RED). However, second-generation biofuels have, in general, a greater potential to reduce the emissions, provided there is no LUC. Third-generation biofuels do not represent a feasible option at present state of development as their GHG emissions are higher than those from fossil fuels. As also discussed in the paper, several studies show that reductions in GHG emissions from biofuels are achieved at the expense of other impacts, such as acidification, eutrophication, water footprint and biodiversity loss. The paper also investigates the key methodological aspects and sources of uncertainty in the LCA of biofuels and provides recommendations to address these issues.

Highlights

  • Greenhouse gas (GHG) emissions from transport have been increasing at a faster rate than from any other sector [1]

  • As first-generation biofuels may involve land-use change (LUC), which in turn can affect significantly the total global warming potential (GWP), the results reported in the literature are discussed first for the cases without and with LUC

  • life cycle assessment (LCA) is widely used as a tool to estimate GWP and other environmental impacts of biofuels

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Summary

IntroductionExpand/Collapse icon

Greenhouse gas (GHG) emissions from transport have been increasing at a faster rate than from any other sector [1]. To reduce dependence on petroleum-based fuels, as well as to mitigate climate change, biofuels are viewed widely as promising alternative transportation fuels. Until the 1940s, biofuels were seen as viable transport fuels and bioethanol blends, such as Agrol, Discol and Monopolin, were commonly used in the USA, Europe and other regions [3]. During the late 1990s, with the rise in crude oil prices and concerns over energy security, the USA and many nations in Europe developed policies in support of domestic biofuel industries [5]. The interest in biofuels further increased in the past decade with the development of policies on climate change mitigation and strategies to reduce GHG emissions from the transport sector. The most notable are Renewable Fuel Standard (RFS) [7] in the USA and the Renewable Energy Directive (RED) in Europe [8]

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In the current era of energy transition, the developmentof syntheticfuel production pathways has revolutionized the prospects for sustainingcarbon-based hydrocarbon fuels in the transportation sector. Notably,technologies such as Power-to-X (PTX) and biofuels have emerged aspromising solutions, fostering cleaner fuels with reduced carbon intensity.However, it is imperative to note that synthetic fuels like e-gasoline,e-ATF, and e-diesel generated via PTX methods, along with biofuels,may possess distinct physiochemical properties compared to their conventionalcrude oil-derived counterparts. Achieving the requisite fuel quality,performance standards, and adherence to stringent environmental regulationsdemands the incorporation of environmentally friendly additives. Thisreview aims to offer a comprehensive review of potential green additivesfor use in synthetic and biofuels, ensuring that they meet necessaryfuel properties and performance criteria. This approach not only addressesthe immediate need for cleaner transportation fuels but also alignswith the global imperative of achieving net-zero emissions targets.

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Arctic melting is an effect of climate change; the use of fossil fuels in marine shipping emits large amounts of air emissions that impact climate change, and Arctic aquatic and human life. Swedish pulp and paper mills generate large amounts of waste and side streams that could be utilized. The production of forest-based biofuel may be a promising solution to achieve sustainable Arctic marine shipping. This review highlights the socio-economic impacts associated with the production of forest-based biofuel in Sweden, the related opportunities, challenges, knowledge gaps, and further need of research. From the economic perspective, it was found that the production and use of forest-based biofuel have short and long-term economic sustainability benefits: (a) short-term benefits, the use of the waste and side streams of the pulp and paper industry is a low-cost available feedstock, unlike first-generation biofuel from crops like corn forest-based biofuels neither require additional land use, water resources nor compete with food. (b) Long-term benefits: (i) the Swedish shipping sector depends on imported fossil fuels, these new biofuels can replace partly those imported fossil fuels that will reduce shipping costs, and generate economic benefits for local consumers. (ii) Usage of forest-based biofuels as blends with conventional fuels in existing engines will reduce greenhouse gas emissions from the Arctic shipping to the set limits in the region. (iii) One of the important socio-economic impacts of forest-based biofuel production and use is the new job creation and employment opportunities that will impact the local communities and livelihoods of indigenous people in the area. From a societal perspective, stakeholder involvement is essential to address the sustainability challenges of biofuel production: EU policymakers need to encourage the production and use of biofuels by developing policies that promote biofuel use. Further studies are needed to develop more efficient and low-cost biofuel production routes, more investments in related research and development are required as well. Local indigenous communities must be involved in the decision-making process through surveys, local dialogues, and research studies. The production of forest-based biofuels has great potential and many social-economic impacts alongside the environmental benefits.

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The growing world population and enhanced dependence on non-renewable sources of energy ultimately led to declining resources, climate change, and increasing carbon emissions. Such an impact of carbon-positive non-renewable energy-based economy has made countries look for more sustainable and cleaner energy sources. Biomass-based renewable energy sources have the potential to reverse climate change with net negative carbon emissions. Perennial grasses like miscanthus, switchgrass, giant red etc. which do not compete with food crops for space, offer a prospective substitute for first-generation feedstocks. The rising concept of circular economy can further curtail the carbon footprint by converting biorefinery-based waste into valuable bio-products. In biofuel generation by microorganisms, there is significant decrease in greenhouse gas emissions when compared to traditional methods. Because of their remarkable capacity to reduce waste production and their intrinsic low carbon footprint, microbes play a crucial role in reducing emissions. Carbon negative energy systems present a scenario to limit global temperatures below a certain limit to avoid determinantal effects over humanity and ecosystems. The review article has emphasized the utility of lignocellulosic biomass, integration of biorefinery based infrastructures with designed microbes and metabolic pathways for bringing down the carbon footprint and achieve sustainability and security in energy sector.

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