Abstract

This study investigates favorable sorption of several environmentally significant aromatic anions, such as pentachlorophenate, benzene and naphthalene sulfonates, onto polymeric anion exchangers. Such favorable sorption processes are unique because they are all endothermic and entropy driven. The sorption behaviors of these aromatic anions are greatly influenced by both hydrophobic and ionic properties. The sorption of the aromatic anions onto the anion exchanger follows ion exchange stoichiometry, but the ion exchange selectivity is determined by concurrent hydrophobic interactions. The ion exchange selectivity in favor of the aromatic anions can be reduced and reversed in cosolvents. The cosolvent effects on the ion exchange selectivity are correlated to Lewis acidity and basicity of cosolvents.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.