Abstract

The molar enthalpies of solution of ionic liquid 1-methyl-3-butylimidazolium tetrafluoroborate (BMIBF 4) in water at various molalities were determined by calorimetry at 298.15 K. Pitzer's electrolyte solution theory was used to obtain the molar solution enthalpy of BMIBF 4 at infinite dilution, Δ s H m 0 = 26.82 ± 0.26 kJ / mol .

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