Abstract
The ionic liquid BMIInCl 4 was prepared by mixing 1-methyl-3-butylimidazolium chloride (BMIC) with InCl 3. The molar solution enthalpies of BMIC and BMIInCl 4 at various molalities were determined by the solution reaction isoperibol calorimeter in water at 298.15 K. In terms of Pitzer's electrolyte solution theory, the molar solution enthalpy of BMIC and BMIInCl 4 at infinite dilution, Δ s H m ° and the parameters: β MX ( 0 ) L , β MX ( 1 ) L and C MX ϕ L were obtained. Then the values of apparent relative molar enthalpy ϕ L and relative partial molar enthalpies of solute (BMIC and BMIInCl 4), L 2, were calculated, respectively. In terms of values of Δ s H m ° of BMIC, BMIInCl 4 and InCl 3, the enthalpy change for the reaction: BMIC + InCl 3 → BMIInCl 4 was obtained.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
