Enhancing the Efficiency of Solar Cells Based on TiO2 and ZnO Photoanodes Through Copper Oxide: A Comparative Study Using Vitis labrusca Extract and N3 Ruthenium Dye

Abstract

This study investigates the effects of varying CuO doping concentrations on the performance of titanium dioxide (TiO2)-based or zinc oxide (ZnO)-based dye-sensitized solar cells (DSSCs). TiO2 or ZnO mixed with CuO at different weight percentages (0–50 wt %) was employed as photoanodes in DSSCs, prepared via mechanical mixing. X-ray diffraction analysis revealed the structural changes, showing that as the CuO content increased in the hybrid, the CuO peaks (notably at 35.5° and 38.7°) became more prominent. Morphological and elemental characterizations were conducted using SEM and XRF, respectively. The solar cells were photosensitized by Vitis lasbrusca (V.L.) extract and N3 dye. The presence of anthocyanin molecules in the extracted V.L. was confirmed using UV-VIS and FTIR spectroscopy. The electrochemical characterization demonstrated optimal solar conversion efficiencies at a 20% doping level for both photosensitizers. Specifically, in the V.L. dye, TiO2-CuO achieved a conversion efficiency of 7.18%, and ZnO-CuO reached 5.77%. In the N3 dye, TiO2-CuO showed an efficiency of 11.34%, and ZnO-CuO, 9.55%. Notably, undoped photoanodes displayed a significantly lower photovoltaic performance: for V.L. dye, TiO2 showed 1.12% and ZnO 0.87%; for N3 dye, TiO2 showed 6.02% and ZnO 4.39%. Doping was therefore effective, yielding up to a seven-fold increase in performance in the case of V.L. with TiO2, compared to undoped DSSCs. The results demonstrate that using the hybrid photoanode led to a considerable increase in performance compared to using only TiO2 or ZnO photoanodes, highlighting the potential of DSSCs as sustainable energy sources.