Enhancing phase identification in waste-to-energy fly ashes: Role of Raman spectroscopy, background fluorescence, and photobleaching

Abstract

Waste-to-Energy (WTE) facilities incinerate ∼11% (∼ 222 Mt) of global solid waste, generating bottom and fly ashes. Landfilling these ashes is costly, and risks releasing contaminants into the environment. Instead, using WTE ashes in secondary industrial applications can circumvent such environmental risks. However, their secondary use is restricted by their inconsistent mineralogy, which may vary due to fluctuating waste composition and combustion conditions. Therefore, there is a need for rapid and reliable monitoring of WTE fly ash mineralogy. Here, we evaluate the employment of Raman spectroscopy for that purpose. Our initial investigation of 12 unique WTE fly ashes resulted in excessive fluorescence, rendering key Raman peaks obscure. To address this issue, we report that a mere 2 min of photobleaching can significantly reduce this fluorescence, facilitating the detection of calcite, calcium sulfate, zincite, and carbon – phases previously undetectable in original spectra. These results show the potential of Raman spectroscopy for rapid monitoring of WTE fly ash mineralogy, which could be beneficial in diverting these ashes from landfill.