Waste to concrete material: Potential Study of Chemical Characterization of Coal Fly Ash and Bottom Ash

Abstract

This research focuses on the chemical properties of coal fly ash (CFA) and coal bottom ash (CBA) obtained from Sultan Azlan Shah Power Plant and compares them with the characteristics of ordinary Portland cement (OPC). Coal has been recognised as a significant fuel source in Malaysia, where it is extensively employed in the creation of steel, cement, and power. When coal is burned to create power, several different types of coal ash are created, including fly ash, bottom ash, boiler slag, and clinker. Fly and bottom ash, however, are the main coal ash waste products that have been created. In an effort to create sustainable concrete from waste, a number of studies have been carried out to ascertain the chemical characteristics of fly and bottom ash. These tests include Energy Disperse X-Ray (EDX), Mineralogy (XRD), and X-Ray Fluorescence (XRF). From the SEM result, fly ash has smaller particles and a spherical, uniform shape than bottom ash and cement. Fly and bottom ash from the Sultan Azlan Shah power plant contain a number of elements, including Silicon (Si), Aluminium (Al), Oxygen (O), Calcium (Ca), Titanium (Ti), Iron (Fe), Magnesium (Mg), Potassium (K), Carbon (C), and Sodium, according to Energy Dispersive X-Ray (EDX) test. The fly ash is primarily an amorphous material, with the presence of quartz crystalline phase (SiO2) at 24.3% and bottom ash at 31.1%, according to X-ray Diffraction (XRD) data. For the mullite phase (3AlO3.2SiO2), fly and bottom ash show results of 24.9% and 14.5%, respectively. According to an X-ray fluorescence (XRF) investigation, the main constituents of fly and bottom ash are silica, iron, and alumina. Fly ash is classified as Class F because it has a high concentration of SiO2, Al2O3, and Fe2O3 while OPC has a high CaO value. With the right composition and material preparation, CFA and CBA from the Sultan Azlan Shah Power Plant can be used as a cement replacement in concrete.