Abstract
Calcium sulfoaluminate belite (CSAB)-based cement exhibits useful properties such as low CO2 footprint, high early-age strength and shrinkage compensating behavior. Our previous study examined the mechanism of carbonation in CSAB-based binder and reported a higher degree of carbonation in CSAB-based binder compared to Portland cement (PC) binder. This study examines the admixing strategies to improve the carbonation resistance of CSAB-based binders. The addition of gypsum or calcium hydroxide reduced the carbonation depth (in natural and accelerated environments) in the CSAB binder. Gypsum addition reduced the pH and resulted in pore refinement. Whereas calcium hydroxide addition increased the pH and promoted the formation of monosulfate (AFm). Although the carbonation depth was reduced in the presence of gypsum or calcium hydroxide, the addition of calcium hydroxide offered a better admixing strategy due to its higher pH which is crucial for the passivation of reinforcement.
Published Version
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