Abstract
Novel Er3+/Yb3+ co-doped transparent glass-ceramics (GCs) containing orthorhombic NaZnPO4 nanocrystals (NCs) were successfully prepared for the first time by a conventional melt-quenching and subsequent heating. Under 980nm laser prompting, the GC samples produced intense red and green up-conversion emissions. The emission intensities varied with Yb3+ concentration and heat treatment conditions. Optimum emission intensities were obtained for the sample with 2mol% of Yb3+ heat treated at 580°C for 4h. Furthermore, the temperature dependent fluorescence intensity ratio (FIR) of thermally coupled emitting states (4S3/2, 2H11/2) in Er3+/Yb3+ co-doped GCs was evaluated under 980nm. A high relative temperature sensitivity of 1.329% K−1 was obtained at 303K and the maximal absolute temperature sensitivity at 612K was evaluated to be 5.732 × 10−3K−1. It is expected that the as-fabricated GCs containing NaZnPO4 NCs are an efficient up-conversion material with potential application in optical temperature sensor.
Published Version
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