Enhanced Titania Photocatalyst on Magnesium Oxide Support Doped with Molybdenum

Abstract

Titania photocatalysts supported on mesoporous MgO carriers doped with Mo(VI) ions were prepared and characterized by XRD, BET nitrogen adsorption, FT-IR, and EPR methods. The photocatalytic activity was evaluated by bleaching an aqueous dye solution in the presence of a dispersed photocatalyst and by bleaching the dry surface of a solid tablet of photocatalyst using rhodamine B and nigrosin as model organic pollutants. It was established that TiO2 photocatalyst based on MgO carrier doped with 1 wt.% Mo(VI) ions, with the ratio of MgO:TiO2 = 1:0.5, possessed the highest activity under UV radiation. The increase in the content of molybdenum up to 10 wt.% leads to the formation of a MoO3 nanophase on the MgO surface, the formation of an isotype n–n heterojunction at the MoO3/TiO2 interface, and photocatalytic activity under the action of visible light.