Enhanced photocatalytic degradation performance of new and stable 2D/3D Ln-MOFs for tetracycline under visible light

Abstract

Rational design of lanthanide metal-organic frameworks (Ln-MOFs) with high stability is of great significance for multifunctional applications. Ln-MOFs have attracted extensive attention in the field of photocatalysis due to their large specific surface area and strong visible light efficiency. In this paper, two 2D/3D Ln-MOFs with different spatial configurations have been successfully synthesized under solvothermal conditions, namely [La(HL)(H2O)]n·3H2O (1), [Er(HL)·3/2(H2O)]n·3/2H2O (2), where H4L = 5-(bis(3-carboxybenzyl)amino)isophthalic acid. Their structures were determined by X-ray single crystal diffraction analysis, and further characterized by XRD analysis and IR spectroscopy. The complex 1 shows layered structure, which extends into a three-dimensional (3D) supramolecular network by π-π interactions, the complex 2 exhibit 3D network structures with a Schläfli symbol of 412·63 topologies, respectively. BET test results showed that there were carboxylic acid groups without coordination in the structure of complex 1, with abundant active sites and higher adsorption activity than complex 2, which would promote the effective contact and reaction between the photocatalyst and tetracycline (TC), thus improving the photocatalytic efficiency of complex 1. Under visible light irradiation, complex 1 showed good photocatalytic degradation of TC, and the degradation rate of TC could reach 75.54% under 120 min. This can be attributed to the effective separation of photogenerated electron-hole pairs and adsorption properties of complex 1. This study provides a new idea for MOFs as an efficient photocatalyst to degrade antibiotic pollutants.