Enhanced performance of solid oxide fuel cells using BaZr0.2Ce0.7Y0.1O3−δ thin films

Abstract

Abstract Thin-film BaZr 0.2 Ce 0.7 Y 0.1 O 3−δ (BZCY) is a promising electrolyte material for intermediate-temperature solid oxide fuel cells. However, a major drawback is its poor adhesion to porous electrodes. For achieving a high adhesion of thin BZCY films to anodes, a mixed electrolyte containing La 0.80 Sr 0.20 Ga 0.80 Mg 0.20 O 3−δ (LSGM) and BZCY is deposited onto a porous NiO–BZCYYb anode, followed by the deposition of a 4 μm-thick BZCY electrolyte layer over the mixed electrolyte layer by e-beam vapor deposition. The formation of a fully dense and well-adhered BZCY layer is confirmed. The prepared cell exhibits excellent potential for achieving high power densities with various fuels. The maximum power densities of a single cell are 1.21, 0.93, and 0.76 W cm −2 at 650 °C with hydrogen, methane, and biogas, respectively. Furthermore, the maximum power densities are 0.26, 0.12, and 0.21 W cm −2 at 500 °C with hydrogen, methane, and biogas, respectively. The ionic conductivities of the electrolyte layer are 1.2 × 10 −2 S cm −1 and 3.1 × 10 −3 S cm −1 at 650 and 500 °C respectively, with an activation energy of 0.46 eV.