Abstract

The phase behavior and the properties of carbon dioxide confined in an ordered mesoporous carbon (CMK-3) during freezing near the bulk triple point have been investigated by in situ total neutron scattering. The CO2 condensed in the mesopores of CMK-3 is found to be in a much densified state comparable with the bulk dry ice. So far, CO2 densification effects have been observed only in microporous carbon materials.

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