Enhanced Adsorption of Rhodamine B on Biomass of Cypress/False Cypress (Chamaecyparis lawsoniana) Fruit: Optimization and Kinetic Study

Abstract

Many industries use various dyes to beautify their products and discharge the waste into the water without proper treatment. Such wastewater is not only dangerous for aquatic life but it is also toxic to human life and can cause numerous problems, such as skin diseases, and some dyes are carcinogenic or even mutagenic as well. Rhodamine-B (RhB) is one of those synthetic organic dyes which is widely used in textile, paper making, leather manufacturing, stained glass work, cosmetics, and many other industries owing to its high tinting strength, high stability, and bright colour. Therefore, it is essential to either remove or reduce its concentration before releasing it into aquatic streams, as well as to minimize or control the cause of several diseases. Several physical and chemical methods have been used for the removal of different dyes from wastewater; nevertheless, adsorption is one of the best techniques used for the removal of dyes due to its high efficiency and low cost. In this regard, we used Chamaecyparis lawsoniana (C. lawsoniana) fruit as a bio-adsorbent for the removal of RhB from an aqueous solution. An 85.42% dye adsorption was achieved at optimized conditions (pH 2, 40 ppm initial dye concentration, 105 min, and 50 mg adsorbent). Adsorption occurs by pseudo-second-order kinetics, according to kinetic studies. Several samples from various sources, including tap water, distilled water, river water, and filtered river water, were tested for RhB removal, and the study revealed good results even in river water. Thus, C. lawsoniana fruit can be used for its real-world application.