Enhanced adsorption and catalytic peroxymonosulfate activation by metal-free N-doped carbon hollow spheres for water depollution

Abstract

Rational design of metal-free carbon-based heterogeneous catatlyst for wastewater remediation via peroxymonosulfate (PMS) activation is highly desirable. Here, hollow structured porous carbon with abundant N, a high graphitization degree, and a large specific surface area and pore volume (1301 m2/g and 1.12 cm3/g) was synthesized by the pyrolysis of core–shell structured composites consisting of polystyrene (PS) cores and Zeolitic imidazolate frameworks-8 (ZIF-8) shells. The hollow structured carbon (CPS@ZIF-8) was characterized thoroughly and applied for phenol degradation by the activation of PMS. The effects of operation conditions such as the catalyst and PMS dose, phenol concentration, initial pH, and temperature on phenol removal were investigated comprehensively. Moreover, the main reactive species involved in phenol oxidation were investigated, and a plausible mechanism for the degradation of phenol is proposed. The results show that CPS@ZIF-8 exhibited an excellent phenol adsorption and degradation performance, which can be mainly ascribed to its large surface area, abundance of nitrogen and hollow porous structure. Moreover, both the nonradical pathway (involving 1O2) and the radical pathway (involving SO4− and O2−) were found to be involved in the decomposition of phenol.