Abstract
The O− transfer reactions of O3− and CO3− with NO and SO2 were measured as a function of temperature in the range 170–605 K in a variable-temperature flowing afterglow system and as a function of center-of-mass kinetic energy in the range 0.04–2 eV in a flow-drift tube system. The rate constant in each case showed a marked energy dependence. The rate constants measured as a function of temperature were essentially the same as those measured as a function of kinetic energy in He and Ar buffer gases when the comparison is made at the same mean center-of-mass kinetic energy. The results imply that the reactions have negligible vibrational or rotational energy dependence.
Published Version
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